File: SUMARY.WM of Tape: Various/ETH/s10-diss
(Source file text)
- 98 - @ka VI. SUMMARY. ____________ @ke @ba We have shown in this work that the concept of anisotropic relaxation times of the conduction electrons can be used to explain experimental results on the resistivity and the Hall effect in pure and alloyed specimens of indium and aluminum. @be @ba The introduction of small quantities of various impurities has a profound influence on the low field Hall coefficient of both In and Al. In the specific case of In, we showed that these effects could not be explained by considering changes in the Fermi surface brought about by the introduction or removal of extra electrons. @be @ba The only way we can explain these results is in assuming that these various impurities each have their own particular scattering properties, leading to an anisotropy of the relaxation time of the various electronic states on the Fermi surface. @be @ba In the framework of pseudopotential and OPW band structure calculations, we have extended the model potential formalism of Shaw to the description of the proper potential of in impurity in a foreign host crystal and given the parameters to be used in calculating various impurity effects. By extracting the non periodic part of these potentials we then specify a set of characteristic phase shifts for both In and Al. @be - 99 - @ba These phase shifts were then used to define local relaxation times with the help of the approximate methods developed by Sorbello giving the averaged character of the wavefunctions over specific parts of the Fermi surface. @be @ba The fact that we had to discuss effects depending on a magnetic field demands a reconsideration of Sorbello's conduction relaxation time. We have extended his treatment in zero field to the case of the non-quantum field regime. Our result is an exact expression of the conductivity tensor which will be of use in forthcoming numerical calculations. @be @ba In this work we have expanded this tensor in powers of the magnetic field and applied the resulting three first terms to a 3-band model representing the topologically different parts of the Fermi surface. The theoretical results of this model, applied to the resistivity and the low field Hall effect are shown to be in reasonable agreement with data obtained from our experiments and from other sources. @be @ba In the same framework we also give a simplified discussion of the influence of temperature on the Hall coefficient and show that, when Umklapp processes are ignored, a rather good agreement between theory and experiment can be obtained. @be